Cobalt-Phthalocyanine-N-Isolog (Cobalt-tetra-2, 3-Pyridinoporphyrazine and Cobalt-tetra-3, 4-Pyridinoporphyrazine)

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Dichloridobis[2-methyl­sulfanyl-4-(pyridin-2-yl)pyrimidine-κ2 N 3,N 4]cobalt(II)

The asymmetric unit of the title compound, [CoCl(2)(C(10)H(9)N(3)S)(2)], contains one half-mol-ecule with the Co(II) atom situtated on a twofold rotational axis. The Co(II) atom, in an octa-hedral enviroment, is coordinated by four N atoms from two 2-methyl-sulfanyl-4-(pyridin-2-yl)pyrimidine ligands and two Cl atoms.

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trans-Diaqua­bis­[5-carb­oxy-2-(3-pyrid­yl)-1H-imidazole-4-carboxyl­ato-κ2 N 3,O 4]cobalt(II)

In the title complex, [Co(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Co(II) atom is located on an inversion centre and displays a distorted octa-hedral coordination geometry defined by two N,O-bidentate ligands in the equatorial plane and two water mol-ecules in the axial positions. The conformation is stabilized by intra-molecular O-H⋯O hydrogen bonds. Inter-molecular N-H⋯O hydrogen bonds link the ...

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Cobalt phthalocyanine-based submicrometric field-effect transistors

We present performance characteristics of nanoscaled cobalt phthalocyanine-based organic field-effect transistors (OFETs) as a function of channel length. We found a channel length range which maximizes the field effect mobility in a trade-off between the decrease in the number of organic grain boundaries and the increase of the electrode-organic contact region. Further reduction of channel len...

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Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ2 N 3,O 4)cobalt(II) N,N-dimethyl­formamide disolvate

In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Co(II) cation (site symmetry ) is six-coordinated by two 5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ate ligands and two water mol-ecules in a distorted octa-hedral environment. In the crystal structure, the complex mol-ecules and dimethyl-formamide solvent mol-ecules are linked by extensive O-H⋯O and N-H⋯O hydrogen bond...

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cyclo-Tetra-μ-malato-κ16 O,O′,O′′:O′′′-tetra­kis[bis­(1H-benzimidazole-κN 3)cobalt(II)] eicosa­hydrate

The title compound, [Co(4)(C(4)H(4)O(5))(4)(C(7)H(6)N(2))(8)]·20H(2)O, consists of tetra-nuclear Co(II) complexes and disordered uncoordinated water mol-ecules. The tetra-meric complex mol-ecule has symmetry. While two benzimidazole mol-ecules and a tridentate malate dianion coordinate a Co(II) ion, the carboxylate O atom from an adjacent malate dianion bridges the Co(II) ions to complete a dis...

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ژورنال

عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan

سال: 1969

ISSN: 0037-9980,1883-6526

DOI: 10.5059/yukigoseikyokaishi.27.448